Publications
2024
Murayama, S.; Ishimoto, T.; Naka, H.
Inverse Kinetic Isotope Effect in Singlet-to-Triplet Intersystem Crossing Contributes to Greater Robustness of Deuterated Organocatalyst
Bull. Chem. Soc. Jpn. 2024, 97, uoae028. DOI: https://doi.org/10.1093/bulcsj/uoae028Naka, H.
Chemoselective Hydration of Unsaturated Organic Compounds Controlled by Catalyst and Reaction Environment
J. Org. Synth. Chem. Jpn. 2024, 82, 14–26. DOI: 10.5059/yukigoseikyokaishi.82.14 (Award Account)
2023
Mori, S.; Sakurai, S.; Naka, H.; Saito, S.
Metal-Loaded Semiconductor-Photocatalysis of Alcohols for Selective Organic Synthesis: A Personal Account
Synlett 2023, 34, 2361–2373. DOI: 10.1055/a-2124-4037 (Invited Account)Hashiba, Y.; Mori, S.; Huang, I.; Morioka, Y.; Naka, H.; Saito, S.
N-Methylation of Twenty Different alpha-Amino Acid Motifs Using Methanol under Metal-loaded Titanium Dioxide Photocatalysis
Asian J. Org. Chem. 2023, e202300230. DOI: 10.1002/ajoc.202300230 (Invited)Murayama, S.; Li, Z.; Liang, H.; Liu, Y.; Naka, H.; Maruoka, K.
Impact of Catalyst Deuteration on the Reactivity of Chiral Phase-Transfer Organocatalysts
Chem. Eur. J. 2023, 29, e202301866. DOI: 10.1002/chem.202301866
2022
Itoga, M.; Yamanishi, M.; Udagawa, T.; Kobayashi, A.; Maekawa, K.; Takemoto Y.; Naka, H.
Iridium-Catalyzed α-Selective Deuteration of Alcohols.
Chem. Sci. 2022, 13, 8744–8751. DOI: 10.1039/D2SC01805E (Highlighted in Outside Front Cover. DOI: https://doi.org/10.1039/D2SC90156K )Liang, H.; Li, Z.; Liu, Y.; Murayama, S.; Naka, H.; Maruoka, K.
Synthesis of Optically Pure, Deuterated Maruoka Catalysts and Their Chemical Reactivity
Tetrahedron Lett. 2022, 96, 153753. DOI: 10.1016/j.tetlet.2022.153753中寛史
銅ジチオカルバメート錯体のバイオオルガノメタリクス.
月刊「細胞」 2022, 54, 9–12.
2021
Wada, Y.; Akiyama, T.; Harada, K.; Honma, T.; Naka, H.; Saito, S.; Arisawa, M.
Preparation of a Platinum Nanoparticle Catalyst Located Near Photocatalyst Titanium Oxide and Its Catalytic Activity to Convert Benzyl Alcohols to the Corresponding Ethers.
RSC Adv. 2021, 11, 22230–22237. DOI : 10.1039/D1RA00988E中寛史
自己組織化錯体を利用した超分子触媒による還元反応
Organometallic News 2021, 90. (ハイライト、解説記事)
2020
Morioka, Y.; Huang, I.; Saito, S.; Naka, H.
Ag(I)/TiO2-Photocatalyzed N-Methylation of Amino Acids with Methanol.
ChemRxiv Preprint. 2020. DOI: 10.26434/chemrxiv.12588266.v1Naka, H.; Naraoka, A.
Recent Advances in Transfer Hydration of Nitriles with Amides or Aldoximes
Tetrahedron Lett. 2020, 61, 151557. DOI: 10.1016/j.tetlet.2019.151557 (Digest Paper)
2019
Naraoka, A.; Naka, H.
Transfer Hydration of Dinitriles to Diamides.
Synlett 2019, 30, 1977–1980. DOI: 10.1055/s-0039-1690026 (Invited Cluster)Okabe, H.; Naraoka, A.; Isogawa, T.; Oishi, S.; Naka, H.
Acceptor-Controlled Transfer Dehydration of Amides to Nitriles.
Org. Lett. 2019, 21, 4767–4770. DOI: 10.1021/acs.orglett.9b01657Kanda, T.; Naraoka, A.; Naka, H.
Catalytic Transfer Hydration of Cyanohydrins to alpha-Hydroxyamides.
J. Am. Chem. Soc. 2019, 141, 825−830. DOI: 10.1021/jacs.8b12877 (Highlighted in Org. Process Res. Dev. 2019, 23, 114−121. DOI: 10.1021/acs.oprd.9b00036)Kitamura, Y.; Murata, Y.; Oguri, A.; Matsumura, M.; Kakusawa, N.; Naka, H.; Yasuike, S.
Pd-Catalyzed β-Selective C–H Arylation of Thiophenes with Triarylantimony Difluorides.
Asian J. Org. Chem. 2019, 8, 138−143. DOI: 10.1002/ajoc.201800654Wang, L.-M.; Kobayashi, K.; Arisawa, M.; Saito, S.; Naka, H.
Pd/TiO2-Photocatalyzed Self-Condensation of Primary Amines to Afford Secondary Amines at Ambient Temperature.
Org. Lett. 2019, 21, 341−344. DOI: 10.1021/acs.orglett.8b03271 (Highlighted in Front Cover.)
2018
Wang, L.-M.; Jenkinson, K.; Wheatley, A. E. H.; Kuwata, K.; Saito, S.; Naka, H.
Photocatalytic N-Methylation of Amines over Pd/TiO2 for the Functionalization of Heterocycles and Pharmaceutical Intermediates.
ACS Sustainable Chem. Eng. 2018, 6, 15419–15424. DOI: 10.1021/acssuschemeng.8b03855Wang, L.-M.; Morioka, Y.; Jenkinson, K.; Wheatley, A. E. H.; Saito, S.; Naka, H.
N-Alkylation of Functionalized Amines with Alcohols Using a Copper-Gold Mixed Photocatalytic System.
Sci. Rep. 2018, 8, 6931. DOI: 10.1038/s41598-018-25293-zTakada, Y.; Caner, J.; Naka, H.; Saito, S.
Photocatalytic Hydrogenolysis of Allylic Alcohols for Rapid Access to Platform Chemicals and Fine Chemicals.
Pure Appl. Chem. 2018, 90, 167–174. DOI: 10.1515/pac-2017-0501 (Invited Conference Paper)中 寛史
銅錯体を起点としたバイオオルガノメタリクス
理大科学フォーラム, 2018, 403, 8–9 (2018).
2017
Ushimaru, R.; Nishimura, T.; Iwatsuki, T.; Naka, H.
A Fluorinated Cobalt(III) Porphyrin Complex for Hydroalkoxylation of Alkynes.
Chem. Pharm. Bull. 2017, 65, 1000–1003. DOI: 10.1248/cpb.c17-00568Takada, Y.; Caner, J.; Kaliyamoorthy, S.; Naka, H.; Saito, S.
Photocatalytic Transfer Hydrogenolysis of Allylic Alcohols on Pd/TiO2: A Shortcut to (S)-(+)-Lavandulol.
Chem. - Eur. J. 2017, 23, 18025–18032. DOI: 10.1002/chem.201704099Fujie, T.; Okino, S.; Yoshida, E.; Yamamoto, C.; Naka, H.; Kaji, T.
Copper Diethyldithiocarbamate as an Inhibitor of Tissue Plasminogen Activator Synthesis in Cultured Human Coronary Endothelial Cells.
J. Toxicol. Sci. 2017, 42, 553–558. DOI: 10.2131/jts.42.553Kitamura, Y,; Matsumura, M.; Murata, Y.; Yamada, M.; Kakusawa, N.; Tanaka, M.; Okabe, H.; Naka, H.; Obata, T.; Yasuike, S.
A Versatile Synthesis of Triarylantimony Difluorides by Fluorination of Triarylstibanes with Nitrosyl Tetrafluoroborate and Their Antitumor Activity.
J. Fluorine Chem. 2017, 199, 1–6. DOI: 10.1016/j.jfluchem.2017.04.004Shibata, M.; Nagata, R.; Saito, S.; Naka, H.
Dehydrogenation of Primary Aliphatic Alcohols by Au/TiO2 Photocatalysts.
Chem. Lett. 2017, 46, 580–582. DOI: 10.1246/cl.161195中 寛史
鼓動する有機化学反応
化学, 2017, 72 (5), 62−63.
2016
Morioka, Y.; Matsuoka, A.; Binder, K.; Knappett, B. R.; Wheatley, A. E. H.; Naka, H.
Selective Hydrogenation of Arenes to Cyclohexanes in Water Catalyzed by Chitin-Supported Ruthenium Nanoparticles.
Catal. Sci. Technol. 2016, 6, 5801–5805. DOI: 10.1039/C6CY00899BFujie, T.; Murakami, M.; Yoshida, E.; Tachinami, T.; Shinkai, Y.; Fujiwara, Y.; Yamamoto, C.; Kumagai, Y.; Naka, H.; Kaji, T.
Copper Diethyldithiocarbamate as an Activator of Nrf2 in Cultured Vascular Endothelial Cells.
J. Biol. Inorg. Chem. 2016, 21, 263–273. DOI: 10.1007/s00775-016-1337-zFujie, T.; Segawa, Y.; Kimura, T.; Fujiwara, Y.; Yamamoto, C.; Satoh, M.; Naka, H.; Kaji, T.
Induction of Metallothionein Isoforms by Copper Diethyldithiocarbamate in Cultured Vascular Endothelial Cells.
J. Toxicol. Sci. 2016, 41, 225–232. DOI: 10.2131/jts.41.225Fujie, T.; Segawa, Y.; Uehara, A.; Nakamura, T.; Kimura, T.; Yoshida, E.; Yamamoto, C.; Uchiyama, M. Naka, H.; Kaji, T.
Zinc Diethyldithiocarbamate as an Inducer of Metallothionein in Cultured Vascular Endothelial Cells.
J. Toxicol. Sci. 2016, 41, 217–224. DOI: 10.2131/jts.41.217
2015
Tsarev, V. N.; Morioka, Y.; Caner, J.; Wang, Q.; Ushimaru, R.; Kudo, A.; Naka, H.; Saito, S.
N-Methylation of Amines with Methanol at Room Temperature.
Org. Lett. 2015, 17, 2530–2533. DOI: 10.1021/acs.orglett.5b01063Matsuoka, A.; Isogawa, T.; Morioka, Y.; Knappett, B. R.; Wheatley, A. E. H.; Saito, S.; Naka, H.
Hydration of Nitriles to Amides by a Chitin-supported Ruthenium Catalyst.
RSC Adv. 2015, 5, 12152–12160. DOI: 10.1039/C4RA15682JMatsuoka, A.; Sandoval, C. A.; Uchiyama, M.; Noyori, R.; Naka, H.
Why p-Cymene? Conformational Effect in Asymmetric Hydrogenation of Aromatic Ketones with a η6-Arene/Ruthenium(II) Catalyst.
Chem. Asian J. 2015, 10, 112–115. DOI: 10.1002/asia.201402979中 寛史
分子触媒プロセスの開発と GRRM 法
IQCE-NEWS, 2015, 23, 1.中 寛史
分子触媒化学の新潮流
名古屋大学物質科学国際研究センターニュース, 2015, 15, 11.
2014
Caner, J.; Liu, Z.; Takada, Y.; Kudo, A.; Naka, H.; Saito, S.
Synthesis of Propylene from Renewable Allyl Alcohol by Photocatalytic Transfer Hydrogenolysis.
Catal. Sci. Technol. 2014, 4, 4093–4098. DOI: 10.1039/C4CY00329BFujie, T.; Naka, H.; Yamamoto, C.; Shinkai, Y.; Kumagai, Y.; Kaji, T.
Activation of Cellular Defense Mechanism by Organic-Inorganic Hybrid Molecules.
Yakugaku Zasshi. 2014, 134, 813−815. DOI: 10.1248/yakushi.14-00017-8
2013
Liu, Z.; Caner, J.; Kudo, A.; Naka, H.; Saito, S.
Redox-Selective Generation of Aldehydes and H2 from Alcohols under Visible Light.
Chem. - Eur. J. 2013, 19, 9452−9456. DOI: 10.1002/chem.201301347 (Highlighted in Synfacts. 2013, 9, 1138. DOI: 10.1055/s-003-25656)Tachinami, T.; Nishimura, T.; Ushimaru, R.; Noyori, R.; Naka, H.
Hydration of Terminal Alkynes Catalyzed by Water-Soluble Cobalt Porphyrin Complexes.
J. Am. Chem. Soc. 2013, 135, 50−53. DOI: 10.1021/ja310282tTakada, Y.; Matsuoka, A.; Du, Y.; Naka, H.; Saito, S.
Acetals of N,N-Dimethylformamides: Ambiphilic Behavior in Converting Carbon Dioxide to Dialkyl Carbonates.
Chem. Lett. 2013, 42, 146–147. DOI: 10.1246/cl.2013.146中 寛史, 斎藤 進
アルコールとその誘導物質の電子的両性に着目した二酸化炭素の資源化法の開発
二酸化炭素の直接利用最新技術, NTS, pp 103−113 (2013).
2012
Kimura, T.; Yoshida, K.; Yamamoto, C.; Suzuki, M.; Uno, T.; Isobe, M.; Naka, H.; Yasuike, S.; Satoh, M.; Kaji, T.; Uchiyama, M.
Bis(L-cysteinato)zincate(II) as a Coordination Compound that Specifically Induces Metallothionein Gene Transcription Without Inducing Cell-stress-related Gene Transcript.
J. Inorg. Biochem. 2012, 117, 140−146. DOI: 10.1016/j.jinorgbio.2012.07.021
2011
Goto, A.; Naka, H.; Noyori, R.; Saito, S.
One-Pot Nitrile Aldolization/Hydration Operation Giving β-Hydroxy Carboxamides.
Chem. Asian J. 2011, 6, 1740–1743. DOI: 10.1002/asia.201000921Naka, H.; Saito, S.
Aluminum Halides
In Science of Synthesis Knowledge Updates, K. Ishihara Ed.; Thieme: Stuttgart, Vol.2010/4, Section 7.1.3.18, pp 79−92 (2011).Naka, H.; Saito, S.
Aluminum Hydrides
In Science of Synthesis Knowledge Updates, K. Ishihara Ed.; Thieme: Stuttgart, Vol. 2010/4, Section 7.1.2.44, pp 69−77 (2011).
2010
Naka, H.; Keisuke Ito, Masahiro Ueno, Koji Kobayashi, Yoshinori Kondo
Generation of Arylzinc Reagents Through an Iodine–zinc Exchange Reaction Promoted by a Non-metallic Organic Superbase
New J. Chem. 2010, 34, 1700–1706. DOI: 10.1039/C0NJ00202JSandoval, C. A.; Bie, F.; Matsuoka, A.; Yamaguchi, Y.; Naka, H.; Li, Y.; Kato, K.; Utsumi, N.; Tsutsumi, K.; Ohkuma, T.; Murata, K.; Noyori, R.
Chiral eta6-Arene/N-Tosylethylenediamine–Ruthenium(II) Complexes: Solution Behavior and Catalytic Activity for Asymmetric Hydrogenation.
Chem. Asian J. 2010, 5, 806–816. DOI: 10.1002/asia.200900461中 寛史
ベンゼン環とフッ素をつなぐ触媒反応
化学, 2010, 65(3), 62−63.中 寛史
Global COE-RCMS 有機化学国際シンポジウムおよび第 6 回平田記念レクチャー
名古屋大学物質科学国際研究センターニュース, 2010, 11, 10.
Full publication list (2004-) is available on ORCID.